In Ecuador and Peru, geochemical information from Pacific coastal rivers is limited and scarce. Here, we present an unedited database of major element concentrations from five HYBAM observatory stations monitored monthly between 4 and 10 years, and the discrete sampling of 23 Andean rivers distributed along the climate gradient of the Ecuadorian and Peruvian Pacific coasts. Concentration (C) vs. discharge (Q) relationships of the five monitored basins exhibit a clear dilution behavior for evaporites and/or pyrite solutes, while the solute concentrations delivered by other endmembers are less variable. Spatially, the annual specific fluxes for total dissolved solids (TDS), Ca²⁺, HCO₃, K+, Mg²⁺, and SiO₂ are controlled on the first order by runoff variability, while Cl, Na⁺ and SO₄² are controlled by the occurrence of evaporites and/or pyrite. The entire Pacific basin in Ecu...

The geochemistry of riverine sediments exported to the oceans is important for paleo-hydro-climatic reconstruction. However, climate reconstruction requires a good understanding of the relationship between geochemistry and hydrological variability and sediment sources. In this study, we analyzed the major elements, the strontium‑neodymium radiogenic isotopes signatures (87Sr/86Sr and εNd) and the mineralogy of the suspended particulate matter (SPM) sampled monthly during two hydrologic years (2007–2008, a wet year, and 2010–2011, a normal hydrological year) upstream the Tumbes River outlet. The hydroclimate of this Ecuador-Peru binational basin is particularly sensitive to ENSO (El Niño Southern Oscillation) eventWhile mineralogy (dominated by illite) and the chemical alteration index (from 75 to 82) remain almost constant along the two hydrological years, 87Sr/86Sr (0.7115 to 0....