Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method

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Peru has several foods with high lipid content (especially oils), rich in omega fatty acids (ω-3 and ω-6) that are widely studied for their anti-inflammatory (ω-3) and pro-inflammatory (ω-6) effects. However, ω-3 and ω-6 are susceptible to oxidation resulting in accelerated deterioration of the oils...

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Autores: Villanueva López, Eudes, Aguirre Vargas , Elza Berta, Hurtado Soria , Beetthssy Zzussy, Pantoja Tirado, Lucia, Ore Quiroz, Harold Pawel Johao, Ortecho Llanos, Ronald, Álvarez Ticllasuca, Adiel, Torres Huamaní , José
Formato: artículo
Fecha de Publicación:2023
Institución:Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo
Repositorio:Tayacaja
Lenguaje:español
OAI Identifier:oai:ojs.unat.edu.pe:article/213
Enlace del recurso:https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213
Nivel de acceso:acceso abierto
Materia:Aceites vegetales
estabilidad oxidativa
omegas
autooxidación
rancimat
Vegetable oils
oxidative stability
autoxidation
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oai_identifier_str oai:ojs.unat.edu.pe:article/213
network_acronym_str REVUNAT
network_name_str Tayacaja
repository_id_str
dc.title.none.fl_str_mv Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
Cinética de la oxidación de aceites derivados de alimentos peruanos ricos en ácidos grasos ω-3 y ω-6 mediante el método Rancimat
title Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
spellingShingle Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
Villanueva López, Eudes
Aceites vegetales
estabilidad oxidativa
omegas
autooxidación
rancimat
Vegetable oils
oxidative stability
omegas
autoxidation
rancimat
title_short Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
title_full Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
title_fullStr Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
title_full_unstemmed Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
title_sort Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat method
dc.creator.none.fl_str_mv Villanueva López, Eudes
Aguirre Vargas , Elza Berta
Hurtado Soria , Beetthssy Zzussy
Pantoja Tirado, Lucia
Ore Quiroz, Harold Pawel Johao
Ortecho Llanos, Ronald
Álvarez Ticllasuca, Adiel
Torres Huamaní , José
author Villanueva López, Eudes
author_facet Villanueva López, Eudes
Aguirre Vargas , Elza Berta
Hurtado Soria , Beetthssy Zzussy
Pantoja Tirado, Lucia
Ore Quiroz, Harold Pawel Johao
Ortecho Llanos, Ronald
Álvarez Ticllasuca, Adiel
Torres Huamaní , José
author_role author
author2 Aguirre Vargas , Elza Berta
Hurtado Soria , Beetthssy Zzussy
Pantoja Tirado, Lucia
Ore Quiroz, Harold Pawel Johao
Ortecho Llanos, Ronald
Álvarez Ticllasuca, Adiel
Torres Huamaní , José
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Aceites vegetales
estabilidad oxidativa
omegas
autooxidación
rancimat
Vegetable oils
oxidative stability
omegas
autoxidation
rancimat
topic Aceites vegetales
estabilidad oxidativa
omegas
autooxidación
rancimat
Vegetable oils
oxidative stability
omegas
autoxidation
rancimat
description Peru has several foods with high lipid content (especially oils), rich in omega fatty acids (ω-3 and ω-6) that are widely studied for their anti-inflammatory (ω-3) and pro-inflammatory (ω-6) effects. However, ω-3 and ω-6 are susceptible to oxidation resulting in accelerated deterioration of the oils. The objective of this work was to determine the oxidative stability index (OSI) of vegetable (seeds) and animal (anchoveta) oils from Peru, with high ω-3 and ω-6 contents, in order to compare oxidation kinetic parameters and shelf life. For this purpose, the Rancimat accelerated oxidation method was used, whose working parameters were: air flow (F = 25 L/h), sample weight (M = 3 g) and temperature range (T = 60-140 °C). The results indicated that the OSI values, as well as the shelf-life projection (T = 25°C) were in the following order: olive oil > chestnut > sesame > sacha inchi > flaxseed > chia > fish. The kinetic parameters of rate constant (k), activation energy (Ea), enthalpy (∆H), entropy (∆S) and temperature acceleration factor (Q10) varied significantly among the oils (p < 0.05). The comparison of the kinetic behavior of the studied samples is key for the development of new products with longer shelf life and increased nutritional value.
publishDate 2023
dc.date.none.fl_str_mv 2023-10-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Artículo revisado por pares
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213
10.46908/tayacaja.v6i2.213
url https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213
identifier_str_mv 10.46908/tayacaja.v6i2.213
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213/193
https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213/194
dc.rights.none.fl_str_mv https://creativecommons.org/licenses/by-nc/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
text/html
dc.publisher.none.fl_str_mv Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo
publisher.none.fl_str_mv Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo
dc.source.none.fl_str_mv TAYACAJA; Vol. 6 No. 2 (2023): Revista de Investigación Científica Tayacaja (Julio - Diciembre); 45 - 53
TAYACAJA; Vol. 6 Núm. 2 (2023): Revista de Investigación Científica Tayacaja (Julio - Diciembre); 45 - 53
Tayacaja; Vol. 6 No. 2 (2023): Tayacaja Scientific Research Jorunal (July - December); 45 - 53
2617-9156
reponame:Tayacaja
instname:Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo
instacron:UNAT
instname_str Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo
instacron_str UNAT
institution UNAT
reponame_str Tayacaja
collection Tayacaja
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Kinetics of the oxidation of oils derived from Peruvian foods rich in ω-3 and ω-6 fatty acids using the Rancimat methodCinética de la oxidación de aceites derivados de alimentos peruanos ricos en ácidos grasos ω-3 y ω-6 mediante el método RancimatVillanueva López, EudesAguirre Vargas , Elza BertaHurtado Soria , Beetthssy ZzussyPantoja Tirado, LuciaOre Quiroz, Harold Pawel JohaoOrtecho Llanos, RonaldÁlvarez Ticllasuca, AdielTorres Huamaní , JoséAceites vegetalesestabilidad oxidativaomegasautooxidaciónrancimatVegetable oilsoxidative stabilityomegasautoxidationrancimatPeru has several foods with high lipid content (especially oils), rich in omega fatty acids (ω-3 and ω-6) that are widely studied for their anti-inflammatory (ω-3) and pro-inflammatory (ω-6) effects. However, ω-3 and ω-6 are susceptible to oxidation resulting in accelerated deterioration of the oils. The objective of this work was to determine the oxidative stability index (OSI) of vegetable (seeds) and animal (anchoveta) oils from Peru, with high ω-3 and ω-6 contents, in order to compare oxidation kinetic parameters and shelf life. For this purpose, the Rancimat accelerated oxidation method was used, whose working parameters were: air flow (F = 25 L/h), sample weight (M = 3 g) and temperature range (T = 60-140 °C). The results indicated that the OSI values, as well as the shelf-life projection (T = 25°C) were in the following order: olive oil > chestnut > sesame > sacha inchi > flaxseed > chia > fish. The kinetic parameters of rate constant (k), activation energy (Ea), enthalpy (∆H), entropy (∆S) and temperature acceleration factor (Q10) varied significantly among the oils (p < 0.05). The comparison of the kinetic behavior of the studied samples is key for the development of new products with longer shelf life and increased nutritional value.Perú posee varios alimentos con alto contenido lipídico (especialmente aceites), ricos en ácidos grasos omega (ω-3 y ω-6) que son ampliamente estudiados por sus efectos antiinflamatorios (ω-3) y proinflamatorios (ω-6). Sin embargo, los ω-3 y ω-6 son susceptibles a la oxidación, lo que provoca un deterioro acelerado de los aceites. El objetivo de este trabajo fue determinar el índice de estabilidad oxidativa (OSI) de aceites vegetales (semillas) y animales (anchoveta) del Perú, con altos contenidos de ω-3 y ω-6, para comparar parámetros cinéticos de oxidación y vida útil. Para ello, se utilizó el método de oxidación acelerada Rancimat, cuyos parámetros de trabajo fueron: flujo de aire (F = 25 L/h), peso de la muestra (M = 3 g) y rango de temperatura (T = 60-140 °C). Los resultados indicaron que los valores de OSI, así como la proyección de la vida útil (T = 25°C) seguían el siguiente orden: aceite de oliva > castaña > sésamo > sacha inchi > linaza > chía > pescado. Los parámetros cinéticos de constante de velocidad (k), energía de activación (Ea), entalpía (∆H), entropía (∆S) y factor de aceleración de la temperatura (Q10) variaron significativamente entre los aceites (p < 0,05). La comparación del comportamiento cinético de las muestras estudiadas es clave para el desarrollo de nuevos productos con mayor vida útil y mayor valor nutritivo.Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morillo2023-10-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArtículo revisado por parestext/htmltext/htmlhttps://revistas.unat.edu.pe/index.php/RevTaya/article/view/21310.46908/tayacaja.v6i2.213TAYACAJA; Vol. 6 No. 2 (2023): Revista de Investigación Científica Tayacaja (Julio - Diciembre); 45 - 53TAYACAJA; Vol. 6 Núm. 2 (2023): Revista de Investigación Científica Tayacaja (Julio - Diciembre); 45 - 53Tayacaja; Vol. 6 No. 2 (2023): Tayacaja Scientific Research Jorunal (July - December); 45 - 532617-9156reponame:Tayacajainstname:Universidad Nacional Autónoma de Tayacaja Daniel Hernández Morilloinstacron:UNATspahttps://revistas.unat.edu.pe/index.php/RevTaya/article/view/213/193https://revistas.unat.edu.pe/index.php/RevTaya/article/view/213/194Derechos de autor 2023 Eudes Villanueva López, Elza Berta Aguirre Vargas , Beetthssy Zzussy Hurtado Soria , Lucia Pantoja Tirado, Harold Pawel Johao Ore Quiroz, Ronald Ortecho Llanos, Adiel Álvarez Ticllasuca, José Torres Huamaní https://creativecommons.org/licenses/by-nc/4.0info:eu-repo/semantics/openAccessoai:ojs.unat.edu.pe:article/2132023-10-11T22:17:03Z
score 12.807258
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