Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.

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The Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activat...

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Detalles Bibliográficos
Autores: José Luis Manrique Murillo, Oscar Christian Medina Carpio, Pamela Lisbeth Manrique Pino, Ever Pavel Macedo Benavente, Danny Pamela Tupayachy Quispe
Formato: artículo
Fecha de Publicación:2020
Institución:Universidad Católica de Santa María
Repositorio:Revistas - Universidad Católica de Santa María
Lenguaje:español
OAI Identifier:oai:ojs.revistas.ucsm.edu.pe:article/281
Enlace del recurso:https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281
Nivel de acceso:acceso abierto
Materia:Adsorción, Biogás
Carbón Activado
Filtros
cascarilla de arroz
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repository_id_str
spelling Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. Evaluación de la capacidad desulfurante de la cascarilla de Oryza sativa transformada como material poroso activado con potencial uso en el tratamiento de biogás.José Luis Manrique MurilloOscar Christian Medina CarpioPamela Lisbeth Manrique PinoEver Pavel Macedo BenaventeDanny Pamela Tupayachy QuispeAdsorción, BiogásCarbón ActivadoFiltroscascarilla de arrozThe Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activation of the husk was carried out in a chemical way using Caustic Potassium at 40% this to lyse lignocellulosic structures; subsequently, a metal oxide was added chemically. The process was optimized through a multilevel factorial design, the maximum yield was recorded by the HRKOH material and was 94.45%, however, due to its low porosity and consequently low retention of pollutants, it was not considered a competent material., the field tests regarding the adsorption of hydrogen sulfide showed similar behaviors between ACarroz, ACFeO and CAC, so it was decided to contrast the material ACARROZ vs CAC by means of isotherms obtaining similar adjustments for both materials; the rice was better adjusted to the Langmuir isotherm showing an R2 of 0.9937 (R in Freundlich = 0.986), similar behavior showed the commercial coal to adjust with a coefficient of determination of 0.9965 for Langmuir and 0.957 for Freundlich.La cascarilla de Oryza sativa suele ser desechada e incinerada sin control por lo cual en la presente investigación se le dio un uso alternativo mediante su transformación como material adsorbente codificado como HRKOH, ACARROZ y ACFeO. (CAC para carbón activado comercial), la activación de la cascarilla se llevó a cabo de manera química utilizando KOH (Potasa Caustica “Clint” en escamas) al 40% esto para lisar estructuras lignocelulósicas; posteriormente se adicionó químicamente un óxido metálico. El proceso se optimizó mediante un diseño factorial multinivel, el rendimiento máximo lo registró el material HRKOH y fue de 94.45%, no obstante debido a su escasa porosidad y consiguientemente baja retención de contaminantes no se le consideró como un material competente. Las pruebas en campo respecto a la adsorción de ácido sulfhídrico mostraron similares comportamientos entre ACarroz, ACFeO y CAC, es así que se optó por contrastar al material ACARROZ vs CAC mediante isotermas obteniéndose ajustes similares para ambos materiales; el ACarroz se ajustó mejor a la isoterma de Langmuir mostrando un R2 de 0.9937 (R2 en Freundlich = 0.986), comportamiento similar mostró el carbón comercial al ajustarse con un coeficiente de determinación de 0.9965 para Langmuir y 0.957 para Freundlich.Universidad Católica de Santa María2020-10-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/28110.35286/veritas.v21i2.281Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-711684-78221684-782210.35286/veritas.v21i2reponame:Revistas - Universidad Católica de Santa Maríainstname:Universidad Católica de Santa Maríainstacron:UCSMspahttps://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281/201Derechos de autor 2020 Veritasinfo:eu-repo/semantics/openAccessoai:ojs.revistas.ucsm.edu.pe:article/2812021-11-19T17:27:02Z
dc.title.none.fl_str_mv Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
Evaluación de la capacidad desulfurante de la cascarilla de Oryza sativa transformada como material poroso activado con potencial uso en el tratamiento de biogás.

title Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
spellingShingle Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
José Luis Manrique Murillo
Adsorción, Biogás
Carbón Activado
Filtros
cascarilla de arroz
title_short Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
title_full Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
title_fullStr Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
title_full_unstemmed Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
title_sort Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
dc.creator.none.fl_str_mv José Luis Manrique Murillo
Oscar Christian Medina Carpio
Pamela Lisbeth Manrique Pino
Ever Pavel Macedo Benavente
Danny Pamela Tupayachy Quispe
author José Luis Manrique Murillo
author_facet José Luis Manrique Murillo
Oscar Christian Medina Carpio
Pamela Lisbeth Manrique Pino
Ever Pavel Macedo Benavente
Danny Pamela Tupayachy Quispe
author_role author
author2 Oscar Christian Medina Carpio
Pamela Lisbeth Manrique Pino
Ever Pavel Macedo Benavente
Danny Pamela Tupayachy Quispe
author2_role author
author
author
author
dc.subject.none.fl_str_mv Adsorción, Biogás
Carbón Activado
Filtros
cascarilla de arroz
topic Adsorción, Biogás
Carbón Activado
Filtros
cascarilla de arroz
description The Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activation of the husk was carried out in a chemical way using Caustic Potassium at 40% this to lyse lignocellulosic structures; subsequently, a metal oxide was added chemically. The process was optimized through a multilevel factorial design, the maximum yield was recorded by the HRKOH material and was 94.45%, however, due to its low porosity and consequently low retention of pollutants, it was not considered a competent material., the field tests regarding the adsorption of hydrogen sulfide showed similar behaviors between ACarroz, ACFeO and CAC, so it was decided to contrast the material ACARROZ vs CAC by means of isotherms obtaining similar adjustments for both materials; the rice was better adjusted to the Langmuir isotherm showing an R2 of 0.9937 (R in Freundlich = 0.986), similar behavior showed the commercial coal to adjust with a coefficient of determination of 0.9965 for Langmuir and 0.957 for Freundlich.
publishDate 2020
dc.date.none.fl_str_mv 2020-10-30
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281
10.35286/veritas.v21i2.281
url https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281
identifier_str_mv 10.35286/veritas.v21i2.281
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281/201
dc.rights.none.fl_str_mv Derechos de autor 2020 Veritas
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Derechos de autor 2020 Veritas
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidad Católica de Santa María
publisher.none.fl_str_mv Universidad Católica de Santa María
dc.source.none.fl_str_mv Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71
Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71
Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71
1684-7822
1684-7822
10.35286/veritas.v21i2
reponame:Revistas - Universidad Católica de Santa María
instname:Universidad Católica de Santa María
instacron:UCSM
instname_str Universidad Católica de Santa María
instacron_str UCSM
institution UCSM
reponame_str Revistas - Universidad Católica de Santa María
collection Revistas - Universidad Católica de Santa María
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