Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas.
Descripción del Articulo
The Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activat...
| Autores: | , , , , |
|---|---|
| Formato: | artículo |
| Fecha de Publicación: | 2020 |
| Institución: | Universidad Católica de Santa María |
| Repositorio: | Revistas - Universidad Católica de Santa María |
| Lenguaje: | español |
| OAI Identifier: | oai:ojs.revistas.ucsm.edu.pe:article/281 |
| Enlace del recurso: | https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281 |
| Nivel de acceso: | acceso abierto |
| Materia: | Adsorción, Biogás Carbón Activado Filtros cascarilla de arroz |
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Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. Evaluación de la capacidad desulfurante de la cascarilla de Oryza sativa transformada como material poroso activado con potencial uso en el tratamiento de biogás.José Luis Manrique MurilloOscar Christian Medina CarpioPamela Lisbeth Manrique PinoEver Pavel Macedo BenaventeDanny Pamela Tupayachy QuispeAdsorción, BiogásCarbón ActivadoFiltroscascarilla de arrozThe Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activation of the husk was carried out in a chemical way using Caustic Potassium at 40% this to lyse lignocellulosic structures; subsequently, a metal oxide was added chemically. The process was optimized through a multilevel factorial design, the maximum yield was recorded by the HRKOH material and was 94.45%, however, due to its low porosity and consequently low retention of pollutants, it was not considered a competent material., the field tests regarding the adsorption of hydrogen sulfide showed similar behaviors between ACarroz, ACFeO and CAC, so it was decided to contrast the material ACARROZ vs CAC by means of isotherms obtaining similar adjustments for both materials; the rice was better adjusted to the Langmuir isotherm showing an R2 of 0.9937 (R in Freundlich = 0.986), similar behavior showed the commercial coal to adjust with a coefficient of determination of 0.9965 for Langmuir and 0.957 for Freundlich.La cascarilla de Oryza sativa suele ser desechada e incinerada sin control por lo cual en la presente investigación se le dio un uso alternativo mediante su transformación como material adsorbente codificado como HRKOH, ACARROZ y ACFeO. (CAC para carbón activado comercial), la activación de la cascarilla se llevó a cabo de manera química utilizando KOH (Potasa Caustica “Clint” en escamas) al 40% esto para lisar estructuras lignocelulósicas; posteriormente se adicionó químicamente un óxido metálico. El proceso se optimizó mediante un diseño factorial multinivel, el rendimiento máximo lo registró el material HRKOH y fue de 94.45%, no obstante debido a su escasa porosidad y consiguientemente baja retención de contaminantes no se le consideró como un material competente. Las pruebas en campo respecto a la adsorción de ácido sulfhídrico mostraron similares comportamientos entre ACarroz, ACFeO y CAC, es así que se optó por contrastar al material ACARROZ vs CAC mediante isotermas obteniéndose ajustes similares para ambos materiales; el ACarroz se ajustó mejor a la isoterma de Langmuir mostrando un R2 de 0.9937 (R2 en Freundlich = 0.986), comportamiento similar mostró el carbón comercial al ajustarse con un coeficiente de determinación de 0.9965 para Langmuir y 0.957 para Freundlich.Universidad Católica de Santa María2020-10-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/28110.35286/veritas.v21i2.281Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-711684-78221684-782210.35286/veritas.v21i2reponame:Revistas - Universidad Católica de Santa Maríainstname:Universidad Católica de Santa Maríainstacron:UCSMspahttps://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281/201Derechos de autor 2020 Veritasinfo:eu-repo/semantics/openAccessoai:ojs.revistas.ucsm.edu.pe:article/2812021-11-19T17:27:02Z |
| dc.title.none.fl_str_mv |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. Evaluación de la capacidad desulfurante de la cascarilla de Oryza sativa transformada como material poroso activado con potencial uso en el tratamiento de biogás. |
| title |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| spellingShingle |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. José Luis Manrique Murillo Adsorción, Biogás Carbón Activado Filtros cascarilla de arroz |
| title_short |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| title_full |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| title_fullStr |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| title_full_unstemmed |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| title_sort |
Evaluation of desulfuring capacity of the Oryza sativa shell transformed as a activated porous material with potential use in the treatment of biogas. |
| dc.creator.none.fl_str_mv |
José Luis Manrique Murillo Oscar Christian Medina Carpio Pamela Lisbeth Manrique Pino Ever Pavel Macedo Benavente Danny Pamela Tupayachy Quispe |
| author |
José Luis Manrique Murillo |
| author_facet |
José Luis Manrique Murillo Oscar Christian Medina Carpio Pamela Lisbeth Manrique Pino Ever Pavel Macedo Benavente Danny Pamela Tupayachy Quispe |
| author_role |
author |
| author2 |
Oscar Christian Medina Carpio Pamela Lisbeth Manrique Pino Ever Pavel Macedo Benavente Danny Pamela Tupayachy Quispe |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Adsorción, Biogás Carbón Activado Filtros cascarilla de arroz |
| topic |
Adsorción, Biogás Carbón Activado Filtros cascarilla de arroz |
| description |
The Oryza sativahusk is usually discarded and incinerated without control, which is why in the present investigation it was given an alternative use by means of its transformation into different adsorbent materials coded as HRKOH, ACARROZ and ACFeO. (CAC for commercial activated carbon), the activation of the husk was carried out in a chemical way using Caustic Potassium at 40% this to lyse lignocellulosic structures; subsequently, a metal oxide was added chemically. The process was optimized through a multilevel factorial design, the maximum yield was recorded by the HRKOH material and was 94.45%, however, due to its low porosity and consequently low retention of pollutants, it was not considered a competent material., the field tests regarding the adsorption of hydrogen sulfide showed similar behaviors between ACarroz, ACFeO and CAC, so it was decided to contrast the material ACARROZ vs CAC by means of isotherms obtaining similar adjustments for both materials; the rice was better adjusted to the Langmuir isotherm showing an R2 of 0.9937 (R in Freundlich = 0.986), similar behavior showed the commercial coal to adjust with a coefficient of determination of 0.9965 for Langmuir and 0.957 for Freundlich. |
| publishDate |
2020 |
| dc.date.none.fl_str_mv |
2020-10-30 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281 10.35286/veritas.v21i2.281 |
| url |
https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281 |
| identifier_str_mv |
10.35286/veritas.v21i2.281 |
| dc.language.none.fl_str_mv |
spa |
| language |
spa |
| dc.relation.none.fl_str_mv |
https://revistas.ucsm.edu.pe/ojs/index.php/veritas/article/view/281/201 |
| dc.rights.none.fl_str_mv |
Derechos de autor 2020 Veritas info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
Derechos de autor 2020 Veritas |
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openAccess |
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application/pdf |
| dc.publisher.none.fl_str_mv |
Universidad Católica de Santa María |
| publisher.none.fl_str_mv |
Universidad Católica de Santa María |
| dc.source.none.fl_str_mv |
Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71 Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71 Veritas; Vol. 21 Núm. 2 (2020): VÉRITAS: Investigación, Innovación y Desarrollo; 67-71 1684-7822 1684-7822 10.35286/veritas.v21i2 reponame:Revistas - Universidad Católica de Santa María instname:Universidad Católica de Santa María instacron:UCSM |
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Universidad Católica de Santa María |
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Revistas - Universidad Católica de Santa María |
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Revistas - Universidad Católica de Santa María |
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La información contenida en este registro es de entera responsabilidad de la institución que gestiona el repositorio institucional donde esta contenido este documento o set de datos. El CONCYTEC no se hace responsable por los contenidos (publicaciones y/o datos) accesibles a través del Repositorio Nacional Digital de Ciencia, Tecnología e Innovación de Acceso Abierto (ALICIA).