Xanthates are widely used in mining industry as collectors for its high affinity towards metal sulfides and precious metal ores. The possibility of using alginate for xanthation has not been explored yet despite the feasibility by the presence of hydroxyl groups alongside the polymeric chains. Therefore, this work aims to evaluate the alginate as a matrix for xanthation and its application on heavy metal ions removal. In order to obtain green materials, important pararmeter were explored such as the effect of reaction time (4–12 h), type of base (NaOH/KOH) and amount of carbon disulfide (2–10%v/v). Xanthated alginates were analyzed by NMR techniques and evidence of β-elimination was detected at 5.45 ppm. Furthermore, the presence of S element was confirmed by EDS mapping technique, while XRD showed a semi-crystalline structure. On the other hand, the chemical shifts of δ(C=S) and Î...

Mining is the most common activity that introduces heavy metal ions into aquatic ecosystems, especially in low income-developing nations where governments are implementing stricter regulations for industrial wastewater. In this context, this work is focused on the application of xanthate-modified alginates for the removal of Pb(II) and Ni(II) from aqueous solutions. In order to confirm the presence of xanthate groups alongside alginate chains, characterization by second-derivative FT-IR was carried out and significance evidence attributed to xanthate groups was found at around 1062–1079 cm−1, 829–845 cm−1 and 620–602 cm−1. In addition to this, thermogravimetric analysis and differential scanning calorimetry were employed to explore thermal properties of modified alginates. According to these results, enthalpy changes (∆H) characteristic of dehydration and collapse of biopol...

This research focused on the synthesis of a functional alginate-based material via chemical modification processes with two steps: oxidation and reductive amination. In previous alginate functionalization with a target molecule such as cysteine, the starting material was purified and characterized by UV-Vis,1 H-NMR and HSQC. Additionally, the application of FT-IR techniques during each step of alginate functionalization was very useful, since new bands and spiked signals around the pyranose ring (1200–1000 cm−1) and anomeric region (1000–750 cm−1) region were identified by a second derivative. Additionally, the presence of C1-H1 of β-D-mannuronic acid residue as well as C1-H1 of α-L-guluronic acid residue was observed in the FT-IR spectra, including a band at 858 cm−1 with characteristics of the N-H moiety from cysteine. The possibility of attaching cysteine molecules to an a...