ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED

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In this study reported some progress in the synthesis of copper ( II ) with ligands monosubstituted benzoiltioureas type , by ico electroquím method. According to this objective we have apl I ied the following procedure has been synthesized ligand 1-phenyl -3 - benzoylthiourea ( H2L ) , which has be...

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Detalles Bibliográficos
Autores: Angulo-Cornejo, J., Beretta-Enciso, G.
Formato: artículo
Fecha de Publicación:1999
Institución:Universidad Nacional Mayor de San Marcos
Repositorio:Revistas - Universidad Nacional Mayor de San Marcos
Lenguaje:español
OAI Identifier:oai:ojs.csi.unmsm:article/4321
Enlace del recurso:https://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321
Nivel de acceso:acceso abierto
Materia:Síntesis electroquímica
benzoiltioureas
complejos de cobre(ll) y cobre (I)
1 H-RMN
13C-RMN
Electrochemical synthesis
copper (II) and copper (I)
1 H-NMR
13C-NMR
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spelling ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTEDSÍNTESIS ELECTROQUÍMICA DE COMPLEJOS DE COBRE(II) CON LIGANDOS TIPO BENZOILTIOUREAS MONOSUSTITUIDASAngulo-Cornejo, J.Beretta-Enciso, G.Beretta-Enciso, G.Síntesis electroquímicabenzoiltioureascomplejos de cobre(ll) y cobre (I)1 H-RMN13C-RMNElectrochemical synthesisbenzoiltioureascopper (II) and copper (I)1 H-NMR13C-NMRIn this study reported some progress in the synthesis of copper ( II ) with ligands monosubstituted benzoiltioureas type , by ico electroquím method. According to this objective we have apl I ied the following procedure has been synthesized ligand 1-phenyl -3 - benzoylthiourea ( H2L ) , which has been characterized by anal y elemental sis, and IR spectroscopy , 1H - NMR , 13C NMR and mass spectrometry . 1H NMR spectroscopy confirms the presence of a hydrogen bond between the proton type of CS- NH group and the oxygen of the CO group . Have synthesized two complexes of copper , the first complex of copper (I) corresponds to a stoichiometric ( 1: 1) [Cu ( I) - L ] n , which was prepared by direct reaction of an ethanolic solution of the ligand and copper acetate ( II ) in equimolar ratio , the second complex was synthesized by the electrochemical method , a Cu ( HL ) 2 stoichiometry . The complexes were characterized by IR spectroscopy , elemental analysis and by measurements of magnetic susceptibilityEn el presente trabajo se reporta algunos avances en la síntesis de complejos de cobre (II) con ligandos tipo benzoiltioureas monosustituidas , por el método electroquím ico. De acuerdo con este objetivo hemos apl icado el siguiente procedimiento : Se ha sintetizado el ligando 1-fenil-3-benzoiltiourea (H2L), el cual ha sido caracterizado mediante el aná li sis elemental , y las espectroscopia IR, 1H-RMN, 13C-RMN, y la espectrometria de masas. La espectroscopia 1H-RMN confirma la presencia de un enlace tipo puente de hidrógeno entre el protón del grupo CS-NH y el oxigeno del grupo CO. Se han sintetizado dos complejos de cobre , el primer complejo de cobre (I) responde a una estequiometria (1 :1) [Cu(I)-L]n , el cual fue preparado por reacción directa entre una solución etanólica del ligando y el acetato de cobre(II) en relación equimolar, el segundo complejo fué sintetizado por-el método electroquímico con una estequiometria Cu(HL)2 . Los complejos fueron caracterizados por espectroscopia IR, análisis elemental y por medidas de susceptibilidad magnéticaUniversidad Nacional Mayor de San Marcos1999-12-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321Revista Peruana de Química e Ingeniería Química; Vol. 2 No. 2 (1999); 84-89Revista Peruana de Química e Ingeniería Química; Vol. 2 Núm. 2 (1999); 84-891609-75991726-2208reponame:Revistas - Universidad Nacional Mayor de San Marcosinstname:Universidad Nacional Mayor de San Marcosinstacron:UNMSMspahttps://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321/3447Derechos de autor 1999 J. Angulo-Cornejo, G. Beretta-Enciso, G. Beretta-Encisohttps://creativecommons.org/licenses/by-nc-sa/4.0info:eu-repo/semantics/openAccessoai:ojs.csi.unmsm:article/43212020-05-08T12:37:36Z
dc.title.none.fl_str_mv ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
SÍNTESIS ELECTROQUÍMICA DE COMPLEJOS DE COBRE(II) CON LIGANDOS TIPO BENZOILTIOUREAS MONOSUSTITUIDAS
title ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
spellingShingle ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
Angulo-Cornejo, J.
Síntesis electroquímica
benzoiltioureas
complejos de cobre(ll) y cobre (I)
1 H-RMN
13C-RMN
Electrochemical synthesis
benzoiltioureas
copper (II) and copper (I)
1 H-NMR
13C-NMR
title_short ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
title_full ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
title_fullStr ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
title_full_unstemmed ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
title_sort ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
dc.creator.none.fl_str_mv Angulo-Cornejo, J.
Beretta-Enciso, G.
Beretta-Enciso, G.
author Angulo-Cornejo, J.
author_facet Angulo-Cornejo, J.
Beretta-Enciso, G.
author_role author
author2 Beretta-Enciso, G.
author2_role author
dc.subject.none.fl_str_mv Síntesis electroquímica
benzoiltioureas
complejos de cobre(ll) y cobre (I)
1 H-RMN
13C-RMN
Electrochemical synthesis
benzoiltioureas
copper (II) and copper (I)
1 H-NMR
13C-NMR
topic Síntesis electroquímica
benzoiltioureas
complejos de cobre(ll) y cobre (I)
1 H-RMN
13C-RMN
Electrochemical synthesis
benzoiltioureas
copper (II) and copper (I)
1 H-NMR
13C-NMR
description In this study reported some progress in the synthesis of copper ( II ) with ligands monosubstituted benzoiltioureas type , by ico electroquím method. According to this objective we have apl I ied the following procedure has been synthesized ligand 1-phenyl -3 - benzoylthiourea ( H2L ) , which has been characterized by anal y elemental sis, and IR spectroscopy , 1H - NMR , 13C NMR and mass spectrometry . 1H NMR spectroscopy confirms the presence of a hydrogen bond between the proton type of CS- NH group and the oxygen of the CO group . Have synthesized two complexes of copper , the first complex of copper (I) corresponds to a stoichiometric ( 1: 1) [Cu ( I) - L ] n , which was prepared by direct reaction of an ethanolic solution of the ligand and copper acetate ( II ) in equimolar ratio , the second complex was synthesized by the electrochemical method , a Cu ( HL ) 2 stoichiometry . The complexes were characterized by IR spectroscopy , elemental analysis and by measurements of magnetic susceptibility
publishDate 1999
dc.date.none.fl_str_mv 1999-12-31
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321
url https://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv https://revistasinvestigacion.unmsm.edu.pe/index.php/quim/article/view/4321/3447
dc.rights.none.fl_str_mv Derechos de autor 1999 J. Angulo-Cornejo, G. Beretta-Enciso, G. Beretta-Enciso
https://creativecommons.org/licenses/by-nc-sa/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Derechos de autor 1999 J. Angulo-Cornejo, G. Beretta-Enciso, G. Beretta-Enciso
https://creativecommons.org/licenses/by-nc-sa/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidad Nacional Mayor de San Marcos
publisher.none.fl_str_mv Universidad Nacional Mayor de San Marcos
dc.source.none.fl_str_mv Revista Peruana de Química e Ingeniería Química; Vol. 2 No. 2 (1999); 84-89
Revista Peruana de Química e Ingeniería Química; Vol. 2 Núm. 2 (1999); 84-89
1609-7599
1726-2208
reponame:Revistas - Universidad Nacional Mayor de San Marcos
instname:Universidad Nacional Mayor de San Marcos
instacron:UNMSM
instname_str Universidad Nacional Mayor de San Marcos
instacron_str UNMSM
institution UNMSM
reponame_str Revistas - Universidad Nacional Mayor de San Marcos
collection Revistas - Universidad Nacional Mayor de San Marcos
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1795238291276038144
score 13.947759
ELECTROCHEMICAL SYNTHESIS OF COMPLEX OF COPPER (II ) WITH TYPE LIGAND BENZOILTIOUREAS MONOSUBSTITUTED
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