Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development

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In this study, we analyzed the contribution of NH4I and glycerol on the ionic conductivity of carboxymethyl κ/ι-hybrid carrageenan-based solid bio-electrolytes. Electrochemical impedance spectroscopy was used to assess the electrochemical properties of the developed biopolymeric films and their inte...

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Detalles Bibliográficos
Autores: Torres F.G., Arroyo J., Alvarez R., Rodriguez S., Troncoso O., López D.
Formato: artículo
Fecha de Publicación:2019
Institución:Consejo Nacional de Ciencia Tecnología e Innovación
Repositorio:CONCYTEC-Institucional
Lenguaje:inglés
OAI Identifier:oai:repositorio.concytec.gob.pe:20.500.12390/486
Enlace del recurso:https://hdl.handle.net/20.500.12390/486
https://doi.org/10.1016/j.matchemphys.2018.11.051
Nivel de acceso:acceso abierto
Materia:Solid electrolytes
Ammonium iodide
Equivalent circuits
Fourier transform infrared spectroscopy
Glycerol
Ion exchange
Ionic conduction in solids
Ionic conductivity
Polyelectrolytes
Amorphous fraction
https://purl.org/pe-repo/ocde/ford#1.04.00
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network_acronym_str CONC
network_name_str CONCYTEC-Institucional
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dc.title.none.fl_str_mv Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
title Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
spellingShingle Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
Torres F.G.
Solid electrolytes
Ammonium iodide
Equivalent circuits
Fourier transform infrared spectroscopy
Fourier transform infrared spectroscopy
Glycerol
Ion exchange
Ionic conduction in solids
Ionic conductivity
Polyelectrolytes
Amorphous fraction
https://purl.org/pe-repo/ocde/ford#1.04.00
title_short Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
title_full Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
title_fullStr Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
title_full_unstemmed Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
title_sort Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development
author Torres F.G.
author_facet Torres F.G.
Arroyo J.
Alvarez R.
Rodriguez S.
Troncoso O.
López D.
author_role author
author2 Arroyo J.
Alvarez R.
Rodriguez S.
Troncoso O.
López D.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Torres F.G.
Arroyo J.
Alvarez R.
Rodriguez S.
Troncoso O.
López D.
dc.subject.none.fl_str_mv Solid electrolytes
topic Solid electrolytes
Ammonium iodide
Equivalent circuits
Fourier transform infrared spectroscopy
Fourier transform infrared spectroscopy
Glycerol
Ion exchange
Ionic conduction in solids
Ionic conductivity
Polyelectrolytes
Amorphous fraction
https://purl.org/pe-repo/ocde/ford#1.04.00
dc.subject.es_PE.fl_str_mv Ammonium iodide
Equivalent circuits
Fourier transform infrared spectroscopy
Fourier transform infrared spectroscopy
Glycerol
Ion exchange
Ionic conduction in solids
Ionic conductivity
Polyelectrolytes
Amorphous fraction
dc.subject.ocde.none.fl_str_mv https://purl.org/pe-repo/ocde/ford#1.04.00
description In this study, we analyzed the contribution of NH4I and glycerol on the ionic conductivity of carboxymethyl κ/ι-hybrid carrageenan-based solid bio-electrolytes. Electrochemical impedance spectroscopy was used to assess the electrochemical properties of the developed biopolymeric films and their interfaces over a wide range of frequencies (1& Hz–7& MHz). X-ray diffractograms demonstrated the increment of the amorphous fraction in the material as the NH4I content increases, suggesting an enhancement of ion transport processes and the successful incorporation of the salt into the host matrix.
publishDate 2019
dc.date.accessioned.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.available.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.issued.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12390/486
dc.identifier.doi.none.fl_str_mv https://doi.org/10.1016/j.matchemphys.2018.11.051
dc.identifier.scopus.none.fl_str_mv 2-s2.0-85059312581
url https://hdl.handle.net/20.500.12390/486
https://doi.org/10.1016/j.matchemphys.2018.11.051
identifier_str_mv 2-s2.0-85059312581
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Materials Chemistry and Physics
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier Ltd
publisher.none.fl_str_mv Elsevier Ltd
dc.source.none.fl_str_mv reponame:CONCYTEC-Institucional
instname:Consejo Nacional de Ciencia Tecnología e Innovación
instacron:CONCYTEC
instname_str Consejo Nacional de Ciencia Tecnología e Innovación
instacron_str CONCYTEC
institution CONCYTEC
reponame_str CONCYTEC-Institucional
collection CONCYTEC-Institucional
repository.name.fl_str_mv Repositorio Institucional CONCYTEC
repository.mail.fl_str_mv repositorio@concytec.gob.pe
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spelling Publicationrp00532600rp00536600rp00533600rp00004400rp00535600rp00534600Torres F.G.Arroyo J.Alvarez R.Rodriguez S.Troncoso O.López D.2024-05-30T23:13:38Z2024-05-30T23:13:38Z2019https://hdl.handle.net/20.500.12390/486https://doi.org/10.1016/j.matchemphys.2018.11.0512-s2.0-85059312581In this study, we analyzed the contribution of NH4I and glycerol on the ionic conductivity of carboxymethyl κ/ι-hybrid carrageenan-based solid bio-electrolytes. Electrochemical impedance spectroscopy was used to assess the electrochemical properties of the developed biopolymeric films and their interfaces over a wide range of frequencies (1& Hz–7& MHz). X-ray diffractograms demonstrated the increment of the amorphous fraction in the material as the NH4I content increases, suggesting an enhancement of ion transport processes and the successful incorporation of the salt into the host matrix.Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - ConcytecengElsevier LtdMaterials Chemistry and Physicsinfo:eu-repo/semantics/openAccessSolid electrolytesAmmonium iodide-1Equivalent circuits-1Fourier transform infrared spectroscopy-1Fourier transform infrared spectroscopy-1Glycerol-1Ion exchange-1Ionic conduction in solids-1Ionic conductivity-1Polyelectrolytes-1Amorphous fraction-1https://purl.org/pe-repo/ocde/ford#1.04.00-1Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes developmentinfo:eu-repo/semantics/articlereponame:CONCYTEC-Institucionalinstname:Consejo Nacional de Ciencia Tecnología e Innovacióninstacron:CONCYTEC20.500.12390/486oai:repositorio.concytec.gob.pe:20.500.12390/4862024-05-30 15:45:22.563http://purl.org/coar/access_right/c_14cbinfo:eu-repo/semantics/closedAccessmetadata only accesshttps://repositorio.concytec.gob.peRepositorio Institucional CONCYTECrepositorio@concytec.gob.pe#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#<Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="87659c76-c894-4f33-9fe8-140917aef884"> <Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843</Type> <Language>eng</Language> <Title>Carboxymethyl κ/ι-hybrid carrageenan doped with NH4I as a template for solid bio-electrolytes development</Title> <PublishedIn> <Publication> <Title>Materials Chemistry and Physics</Title> </Publication> </PublishedIn> <PublicationDate>2019</PublicationDate> <DOI>https://doi.org/10.1016/j.matchemphys.2018.11.051</DOI> <SCP-Number>2-s2.0-85059312581</SCP-Number> <Authors> <Author> <DisplayName>Torres F.G.</DisplayName> <Person id="rp00532" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Arroyo J.</DisplayName> <Person id="rp00536" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Alvarez R.</DisplayName> <Person id="rp00533" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Rodriguez S.</DisplayName> <Person id="rp00004" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Troncoso O.</DisplayName> <Person id="rp00535" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>López D.</DisplayName> <Person id="rp00534" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> </Authors> <Editors> </Editors> <Publishers> <Publisher> <DisplayName>Elsevier Ltd</DisplayName> <OrgUnit /> </Publisher> </Publishers> <Keyword>Solid electrolytes</Keyword> <Keyword>Ammonium iodide</Keyword> <Keyword>Equivalent circuits</Keyword> <Keyword>Fourier transform infrared spectroscopy</Keyword> <Keyword>Fourier transform infrared spectroscopy</Keyword> <Keyword>Glycerol</Keyword> <Keyword>Ion exchange</Keyword> <Keyword>Ionic conduction in solids</Keyword> <Keyword>Ionic conductivity</Keyword> <Keyword>Polyelectrolytes</Keyword> <Keyword>Amorphous fraction</Keyword> <Abstract>In this study, we analyzed the contribution of NH4I and glycerol on the ionic conductivity of carboxymethyl κ/ι-hybrid carrageenan-based solid bio-electrolytes. Electrochemical impedance spectroscopy was used to assess the electrochemical properties of the developed biopolymeric films and their interfaces over a wide range of frequencies (1&amp; Hz–7&amp; MHz). X-ray diffractograms demonstrated the increment of the amorphous fraction in the material as the NH4I content increases, suggesting an enhancement of ion transport processes and the successful incorporation of the salt into the host matrix.</Abstract> <Access xmlns="http://purl.org/coar/access_right" > </Access> </Publication> -1
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