A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process

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This research was supported by the Phosagro/UNESCO/IUPAC Partnership in Green Chemistry for Life (Contract ). JCFRR acknowledges the support of 4500245048FONDECYT and the World Bank (Contract 106-2018).The participation of GL was possible through the Real Life Experience (RLE) program at UTEC. Karin...

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Detalles Bibliográficos
Autores: Larrabure, G., Rodríguez-Reyes, J.C.F.
Formato: revisión
Fecha de Publicación:2021
Institución:Consejo Nacional de Ciencia Tecnología e Innovación
Repositorio:CONCYTEC-Institucional
Lenguaje:inglés
OAI Identifier:oai:repositorio.concytec.gob.pe:20.500.12390/2962
Enlace del recurso:https://hdl.handle.net/20.500.12390/2962
https://doi.org/10.1016/j.mineng.2021.107194
Nivel de acceso:acceso abierto
Materia:Silver
Cyanicidal agent
Cyanide leaching
Gold
Preg-robbing
Refractory ore
https://purl.org/pe-repo/ocde/ford#2.07.05
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network_acronym_str CONC
network_name_str CONCYTEC-Institucional
repository_id_str 4689
dc.title.none.fl_str_mv A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
title A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
spellingShingle A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
Larrabure, G.
Silver
Cyanicidal agent
Cyanide leaching
Gold
Preg-robbing
Refractory ore
https://purl.org/pe-repo/ocde/ford#2.07.05
title_short A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
title_full A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
title_fullStr A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
title_full_unstemmed A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
title_sort A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process
author Larrabure, G.
author_facet Larrabure, G.
Rodríguez-Reyes, J.C.F.
author_role author
author2 Rodríguez-Reyes, J.C.F.
author2_role author
dc.contributor.author.fl_str_mv Larrabure, G.
Rodríguez-Reyes, J.C.F.
dc.subject.none.fl_str_mv Silver
topic Silver
Cyanicidal agent
Cyanide leaching
Gold
Preg-robbing
Refractory ore
https://purl.org/pe-repo/ocde/ford#2.07.05
dc.subject.es_PE.fl_str_mv Cyanicidal agent
Cyanide leaching
Gold
Preg-robbing
Refractory ore
dc.subject.ocde.none.fl_str_mv https://purl.org/pe-repo/ocde/ford#2.07.05
description This research was supported by the Phosagro/UNESCO/IUPAC Partnership in Green Chemistry for Life (Contract ). JCFRR acknowledges the support of 4500245048FONDECYT and the World Bank (Contract 106-2018).The participation of GL was possible through the Real Life Experience (RLE) program at UTEC. Karinna Visurraga is thanked for administrative support.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.available.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.issued.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/review
format review
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12390/2962
dc.identifier.doi.none.fl_str_mv https://doi.org/10.1016/j.mineng.2021.107194
dc.identifier.scopus.none.fl_str_mv 2-s2.0-85115787501
url https://hdl.handle.net/20.500.12390/2962
https://doi.org/10.1016/j.mineng.2021.107194
identifier_str_mv 2-s2.0-85115787501
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Minerals Engineering
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier Ltd
publisher.none.fl_str_mv Elsevier Ltd
dc.source.none.fl_str_mv reponame:CONCYTEC-Institucional
instname:Consejo Nacional de Ciencia Tecnología e Innovación
instacron:CONCYTEC
instname_str Consejo Nacional de Ciencia Tecnología e Innovación
instacron_str CONCYTEC
institution CONCYTEC
reponame_str CONCYTEC-Institucional
collection CONCYTEC-Institucional
repository.name.fl_str_mv Repositorio Institucional CONCYTEC
repository.mail.fl_str_mv repositorio@concytec.gob.pe
_version_ 1839175783836286976
spelling Publicationrp05825600rp08388600Larrabure, G.Rodríguez-Reyes, J.C.F.2024-05-30T23:13:38Z2024-05-30T23:13:38Z2021https://hdl.handle.net/20.500.12390/2962https://doi.org/10.1016/j.mineng.2021.1071942-s2.0-85115787501This research was supported by the Phosagro/UNESCO/IUPAC Partnership in Green Chemistry for Life (Contract ). JCFRR acknowledges the support of 4500245048FONDECYT and the World Bank (Contract 106-2018).The participation of GL was possible through the Real Life Experience (RLE) program at UTEC. Karinna Visurraga is thanked for administrative support.The ongoing depletion of gold and silver-containing ore deposits demands a shift towards the processing of more complex sources. Leaching of gold or silver from these sources, which are named refractory and are typically low-grade, can be complicated due to one or more of the following effects: (1) kinetic or thermodynamic impediments on cyanide diffusion or on the dissolution of minerals, (2) readsorption of leached gold or silver (preg-robbing), and (3) excessive cyanide consumption due to the presence of cyanicidal agents. This article reviews the occurrence of these effects as a function of the elemental composition and compiles strategies to overcome them. The first type of refractory behavior was found to be related to arsenic or antimony sulfides and sulfosalts, manganese oxides, permanganates, iron sulfides, oxides, and hydroxides, tellurides, as well as different sulfur-containing minerals. In general, most kinetic or thermodynamic impediments are addressed by performing intensive grinding and through oxidation processes for sulfides, such as roasting, pressure oxidation, chemical oxidation or biological oxidation. On the other hand, preg-robbing activity was described as common in ores that contain carbonaceous matter, silicates, and sulfides. Strategies to deal with preg-robbing ores often include the destruction or deactivation of the preg-robbing surface, or the addition of another adsorbent to compete with the preg-robber (carbon-in-leach). Finally, cyanicidal agents include sulfides and compounds containing base metals, mainly copper, iron, zinc, and nickel. In the case of sulfides, performing oxidation processes is common, while base metals often require one or more pre-leaching stages in which they can be partially removed from the ore prior to cyanidation. Even though this review intends to serve as a compendium of strategies directed at improving cyanidation processes depending on the nature of the elements present in a feed, a final discussion stressing the importance of developing ore-specific strategies is given. © 2021 Elsevier LtdConsejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - ConcytecengElsevier LtdMinerals Engineeringinfo:eu-repo/semantics/openAccessSilverCyanicidal agent-1Cyanide leaching-1Gold-1Preg-robbing-1Refractory ore-1https://purl.org/pe-repo/ocde/ford#2.07.05-1A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching processinfo:eu-repo/semantics/reviewreponame:CONCYTEC-Institucionalinstname:Consejo Nacional de Ciencia Tecnología e Innovacióninstacron:CONCYTEC20.500.12390/2962oai:repositorio.concytec.gob.pe:20.500.12390/29622024-05-30 16:12:32.413http://purl.org/coar/access_right/c_14cbinfo:eu-repo/semantics/closedAccessmetadata only accesshttps://repositorio.concytec.gob.peRepositorio Institucional CONCYTECrepositorio@concytec.gob.pe#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#<Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="e0870c5d-1caa-4e9c-9157-dcd00c9fc2b3"> <Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843</Type> <Language>eng</Language> <Title>A review on the negative impact of different elements during cyanidation of gold and silver from refractory ores and strategies to optimize the leaching process</Title> <PublishedIn> <Publication> <Title>Minerals Engineering</Title> </Publication> </PublishedIn> <PublicationDate>2021</PublicationDate> <DOI>https://doi.org/10.1016/j.mineng.2021.107194</DOI> <SCP-Number>2-s2.0-85115787501</SCP-Number> <Authors> <Author> <DisplayName>Larrabure, G.</DisplayName> <Person id="rp05825" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Rodríguez-Reyes, J.C.F.</DisplayName> <Person id="rp08388" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> </Authors> <Editors> </Editors> <Publishers> <Publisher> <DisplayName>Elsevier Ltd</DisplayName> <OrgUnit /> </Publisher> </Publishers> <Keyword>Silver</Keyword> <Keyword>Cyanicidal agent</Keyword> <Keyword>Cyanide leaching</Keyword> <Keyword>Gold</Keyword> <Keyword>Preg-robbing</Keyword> <Keyword>Refractory ore</Keyword> <Abstract>The ongoing depletion of gold and silver-containing ore deposits demands a shift towards the processing of more complex sources. Leaching of gold or silver from these sources, which are named refractory and are typically low-grade, can be complicated due to one or more of the following effects: (1) kinetic or thermodynamic impediments on cyanide diffusion or on the dissolution of minerals, (2) readsorption of leached gold or silver (preg-robbing), and (3) excessive cyanide consumption due to the presence of cyanicidal agents. This article reviews the occurrence of these effects as a function of the elemental composition and compiles strategies to overcome them. The first type of refractory behavior was found to be related to arsenic or antimony sulfides and sulfosalts, manganese oxides, permanganates, iron sulfides, oxides, and hydroxides, tellurides, as well as different sulfur-containing minerals. In general, most kinetic or thermodynamic impediments are addressed by performing intensive grinding and through oxidation processes for sulfides, such as roasting, pressure oxidation, chemical oxidation or biological oxidation. On the other hand, preg-robbing activity was described as common in ores that contain carbonaceous matter, silicates, and sulfides. Strategies to deal with preg-robbing ores often include the destruction or deactivation of the preg-robbing surface, or the addition of another adsorbent to compete with the preg-robber (carbon-in-leach). Finally, cyanicidal agents include sulfides and compounds containing base metals, mainly copper, iron, zinc, and nickel. In the case of sulfides, performing oxidation processes is common, while base metals often require one or more pre-leaching stages in which they can be partially removed from the ore prior to cyanidation. Even though this review intends to serve as a compendium of strategies directed at improving cyanidation processes depending on the nature of the elements present in a feed, a final discussion stressing the importance of developing ore-specific strategies is given. © 2021 Elsevier Ltd</Abstract> <Access xmlns="http://purl.org/coar/access_right" > </Access> </Publication> -1
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