One-dimensional nanostructures have shown high photocatalytic efficiency due to their high surface area to volume ratio and charge transfer efficiency. In this work, we have studied the influence of zinc acetate content (zinc acetate to polyvinyl alcohol (PVA) mass ratio) on the photoelectrochemical performance of zinc oxide (ZnO) nanostructures. The nanostructures of ZnO were fabricated on fluorine-doped tin oxide glass substrate by electrospinning of aqueous solution containing different amounts of zinc acetate. The precursor nanofibers of zinc acetate/PVA were converted into polycrystalline ZnO nanostructures with hexagonal wurtzite crystal structure by calcination at 600°C for 3 h. It was found that by increasing the amount of zinc acetate, the diameter of the as-spun precursor fibers increased and their distribution became broader. The mean diameter of the ZnO nanoparticles forming...