The project CIMO North-South-South‘‘PROENV2’’, theAdMAtU–project (AKVA Program) financed by the Academy ofFinland, and HYMEPRO financed by the Finnish FundingAgency for Innovation (Tekes) are acknowledged for the financial support. The National University of Tumbes (ProyectoCanon – Resoluci ?on N80722-2014/UNT-R) and the PeruvianNational Council for Science and Technology (CONCYTEC)(Proyecto. No. 002/PE/2012) are gratefully recognized for theirsupport. The authors also want to thank their home universities for their support.

The National University of Tumbes provided important financial support (Proyecto de Investigacion Docente - Resolucion No 1217-2013/UNT-R). The Academy of Sciences of the Czech Republic and Consejo Nacional de Ciencia, Tecnologia e Innovacion Tecnologica (CONCYTEC) in Peru (joint project reg. No. 002/PE/2012) are also gratefully recognized for their support. The Academy of Finland and the Finnish Funding Agency for Innovation (Tekes) are acknowledged for research funding to the AdMatU project from the Development funds and to the HYMEPRO project, respectively. Thanks to Dr. Gladys Ocharan, Alex Diamond, and Hana Snajdaufova (from ICPF) for technical support and Dr. Tomas Strasak (from ICPF) for help with DFT calculations.

The Academy of Sciences of the Czech Republic and Consejo Nacional de Ciencia, Tecnologia e Innovación Tecno-lógica (CONCYTEC) in Peru (joint project reg. No. 002/PE/ 2012) are gratefully recognized for their support.

Composite material (AC-ZnO) was prepared by growing ZnO nanoparticles during the production of biomass based-activated carbon (AC) via the incorporation of zinc acetate in the process. Comprehensive analyses confirmed the presence of ZnO nanoparticles over the AC surface and described the particular nature of the composite adsorbent. Methylene blue (MB) equilibrium data fitted the Dubinin-Radushkevich model. The MB adsorption capacity was higher for the bare activated carbons (197.9–188.7 mg/g) than the activated carbons with ZnO nanoparticles (137.6–149.7 mg/g). The adsorption of the MB on the adsorbents is physical because the mean adsorption energy (E) is between 1.76 and 2.00 kJ/mol. Experiments that combine adsorption and photocatalysis were carried out with different loads of adsorbents and with and without UV-light exposure. Photocatalytic activity was identified mostly at the...

ZnCl2-activated carbon was prepared using coffee husk for phosphate adsorption in aqueous solutions. Textural, morphological and structural analyses were carried out to characterize the produced materials. XRD detected the presence of ZnO in the activated carbon structure, and the measured nitrogen isotherm showed a micro-macroporous structure with 989 m2/g of specific surface area for this material. Phosphate equilibrium and kinetic experiments were conducted. Equilibrium data fit best to the Dubinin-Radushkevich model (r2≥0.96), with maximum adsorption capacities of 59.38 – 63.87 mg P/g in the pH range between 5 and 9. Intraparticle diffusion was the rate-limiting mechanism of the adsorption.

The utilization of unconventional agricultural wastes to obtain new porous carbonaceous materials, at mild pyrolysis temperatures and without complex procedures, for either water treatment and energy storage applications is important from the economic and environmental perspective. In this study, biochars and hydrochars were prepared from banana rachis, cocoa pod husks, and rice husks at 600 °C-2 h, under nitrogen flux. The prepared materials were characterized to better understand how their morphological, textural, physical-chemical and/or structural properties correlate with their methylene blue (MB) adsorption capacities. The material with the best properties (mainly SBET > 800 m2/g) and MB adsorption capacity was a novel biochar prepared from banana rachis (BW-BC). This novel material was selected for additional kinetics and equilibrium adsorption tests for lead (Pb) along with i...