The aim of this research was to evaluate the anticorrosive properties of alkyd paints and wash primers formulated with zinc tannates containing Tara tannins. Their inhibitory efficiency was compared with paints pigmented with well-known anticorrosive pigments by accelerated corrosion tests (salt spray test, Prohesion test, and sulphur dioxide test), natural exposure tests and some electrochemical techniques (corrosion potential, polarization resistance and impedance measurements). It was demonstrated that the capacity of inhibiting corrosion of zinc tannates is equivalent to that shown by most commercially available conventional pigments, such as zinc phosphate and zinc chromate.

Alkyd paints contain resins derived from vegetable oils. Alkyd resins have regained their importance since they are mostly composed of bio-based constituents recovered from biofuels production and agro-industrial waste. The anticorrosive performance of medium alkyd paints modified with Sacha inchi and linseed oils, and different ratios of glycerol and pentaerythritol, were compared by accelerated corrosion tests (Salt Fog and Sulphur Dioxide tests). This study focuses on comparing the effect of polyalcohol and oil type on physicochemical properties of resin solutions and cured films, and consequently, on the anticorrosive behaviour of paints prepared with the resins under study. Results showed that the mixture of pentaerythritol and Sacha inchi oil improves alkyd resin properties and enhance the anticorrosive performance of alkyd paints in accelerated weathering tests. © 2020 Elsevier B...

The high-unsaturated fatty acid content of Sacha inchi oil (SIO), a perennial plant originally from Peru, has turned it into a potential raw material for the production of alkyd resins. In this study, different proportions of multifunctional polyols were used to prepare air-drying resins. Physicochemical characteristics (acid value, viscosity, colour, density, drying time, and hardness) of alkyds were evaluated. Moreover, FT-IR, TG–DTA, 1H-NMR and 13C-NMR characterization techniques were used. SIO-based alkyd resins prepared with trimethylolpropane exhibited low viscosities, suitable for preparing more manageable high solids protective coatings. © 2021, The Polymer Society, Taipei.