The effects of complex slab geometries on the surrounding mantle flow field are still poorly understood. Here we combine shear wave velocity structure with Rayleigh wave phase anisotropy to examine these effects in southern Peru, where the slab changes its geometry from steep to flat. To the south, where the slab subducts steeply, we find trench‐parallel anisotropy beneath the active volcanic arc that we attribute to the mantle wedge and/or upper portions of the subducting plate. Farther north, beneath the easternmost corner of the flat slab, we observe a pronounced low‐velocity anomaly. This anomaly is caused either by the presence of volatiles and/or flux melting that could result from southward directed, volatile‐rich subslab mantle flow or by increased temperature and/or decompression melting due to small‐scale vertical flow. We also find evidence for mantle flow through the ...