In the present research, modeling and simulation of a distillation column for multicomponent mixtures of hydrocarbons it was performed. The rigorous simulation method proposed Bubble Point is based on an analysis of partition tridiagonal matrix incorporating classical Wang-Henke. For this design the liquid-vapor equilibrium and enthalpies of the mixture to respective stages, from its components thermophysical properties predicted. reports temperatures, compositions and fluxes were prepared column and graphic profiles thereof. The prediction of liquid - vapor equilibrium and enthalpy of a mixture of hydrocarbons, may well be determined by equations of state as are the Peng-Robinson equation, Redlich-Kwong, Soave-Redlich-Kwong, etc. In this paper the equilibrium constants and enthalpies given by literature were used.