Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses

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In the present work, the influence of alkali ions (Li, Na, K) on the structural and spectroscopic properties of silica glasses doped with Sm3+ was investigated. Infrared and Raman spectroscopy techniques were used to investigate the structural properties of the alkali silicate glasses. The optical a...

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Detalles Bibliográficos
Autor: Montoya Matos, Israel Roger
Formato: artículo
Fecha de Publicación:2023
Institución:Universidad de Lima
Repositorio:ULIMA-Institucional
Lenguaje:inglés
OAI Identifier:oai:repositorio.ulima.edu.pe:20.500.12724/19068
Enlace del recurso:https://hdl.handle.net/20.500.12724/19068
https://doi.org/10.3390/ceramics6030109
Nivel de acceso:acceso abierto
Materia:Glass
Ions
Absorption spectra
Luminescence
Raman spectroscopy
Phonons
Lasers
Optoelectronic devices
Alkali metals
Molecular structure
Molecular spectroscopy
https://purl.org/pe-repo/ocde/ford#2.01.00
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dc.title.en_EN.fl_str_mv Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
title Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
spellingShingle Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
Montoya Matos, Israel Roger
Glass
Ions
Absorption spectra
Luminescence
Raman spectroscopy
Phonons
Lasers
Optoelectronic devices
Alkali metals
Molecular structure
Molecular spectroscopy
https://purl.org/pe-repo/ocde/ford#2.01.00
title_short Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
title_full Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
title_fullStr Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
title_full_unstemmed Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
title_sort Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
author Montoya Matos, Israel Roger
author_facet Montoya Matos, Israel Roger
author_role author
dc.contributor.other.none.fl_str_mv Montoya Matos, Israel Roger
dc.contributor.author.fl_str_mv Montoya Matos, Israel Roger
dc.subject.en_EN.fl_str_mv Glass
Ions
Absorption spectra
Luminescence
Raman spectroscopy
Phonons
Lasers
Optoelectronic devices
Alkali metals
Molecular structure
Molecular spectroscopy
topic Glass
Ions
Absorption spectra
Luminescence
Raman spectroscopy
Phonons
Lasers
Optoelectronic devices
Alkali metals
Molecular structure
Molecular spectroscopy
https://purl.org/pe-repo/ocde/ford#2.01.00
dc.subject.ocde.none.fl_str_mv https://purl.org/pe-repo/ocde/ford#2.01.00
description In the present work, the influence of alkali ions (Li, Na, K) on the structural and spectroscopic properties of silica glasses doped with Sm3+ was investigated. Infrared and Raman spectroscopy techniques were used to investigate the structural properties of the alkali silicate glasses. The optical absorption showed bands characteristic of Sm3+ ions in alkali silicate glasses, and this was investigated. The Judd–Ofelt theory was applied to evaluate the phenomenological intensity parameters (O2, O4, and O6) of the optical absorption measurements. The multi-channel visible and near infrared emission transitions originating from the 4G5/2-emitting state of the Sm3+ in alkali silicate glasses with a maximum phonon energy of ~1050 cm-1 were investigated. From the evaluated Judd–Ofelt parameters, radiative parameters such as spontaneous emission probabilities, radiative lifetimes, branching ratios, and stimulated emission cross-sections were calculated. The recorded luminescence spectra regions revealed intense green, orange, red, and near-infrared emission bands, providing new traces for developing tunable laser and optoelectronic devices.
publishDate 2023
dc.date.accessioned.none.fl_str_mv 2023-10-11T20:12:38Z
dc.date.available.none.fl_str_mv 2023-10-11T20:12:38Z
dc.date.issued.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
dc.type.other.none.fl_str_mv Artículo en Scopus
format article
dc.identifier.citation.es_PE.fl_str_mv Montoya Matos, I. R. (2023). Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses. Ceramics, 6(3), 1788-1798. https://doi.org/10.3390/ceramics6030109
dc.identifier.issn.none.fl_str_mv 2571-6131
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12724/19068
dc.identifier.journal.none.fl_str_mv Ceramics
dc.identifier.isni.none.fl_str_mv 0000000121541816
dc.identifier.doi.none.fl_str_mv https://doi.org/10.3390/ceramics6030109
dc.identifier.scopusid.none.fl_str_mv 2-s2.0-85172236792
identifier_str_mv Montoya Matos, I. R. (2023). Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses. Ceramics, 6(3), 1788-1798. https://doi.org/10.3390/ceramics6030109
2571-6131
Ceramics
0000000121541816
2-s2.0-85172236792
url https://hdl.handle.net/20.500.12724/19068
https://doi.org/10.3390/ceramics6030109
dc.language.iso.none.fl_str_mv eng
language eng
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eu_rights_str_mv openAccess
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dc.format.none.fl_str_mv application/html
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.publisher.country.none.fl_str_mv CH
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.source.none.fl_str_mv Repositorio Institucional - Ulima
Universidad de Lima
reponame:ULIMA-Institucional
instname:Universidad de Lima
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instname_str Universidad de Lima
instacron_str ULIMA
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spelling Montoya Matos, Israel RogerMontoya Matos, Israel Roger2023-10-11T20:12:38Z2023-10-11T20:12:38Z2023Montoya Matos, I. R. (2023). Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses. Ceramics, 6(3), 1788-1798. https://doi.org/10.3390/ceramics60301092571-6131https://hdl.handle.net/20.500.12724/19068Ceramics0000000121541816https://doi.org/10.3390/ceramics60301092-s2.0-85172236792In the present work, the influence of alkali ions (Li, Na, K) on the structural and spectroscopic properties of silica glasses doped with Sm3+ was investigated. Infrared and Raman spectroscopy techniques were used to investigate the structural properties of the alkali silicate glasses. The optical absorption showed bands characteristic of Sm3+ ions in alkali silicate glasses, and this was investigated. The Judd–Ofelt theory was applied to evaluate the phenomenological intensity parameters (O2, O4, and O6) of the optical absorption measurements. The multi-channel visible and near infrared emission transitions originating from the 4G5/2-emitting state of the Sm3+ in alkali silicate glasses with a maximum phonon energy of ~1050 cm-1 were investigated. From the evaluated Judd–Ofelt parameters, radiative parameters such as spontaneous emission probabilities, radiative lifetimes, branching ratios, and stimulated emission cross-sections were calculated. The recorded luminescence spectra regions revealed intense green, orange, red, and near-infrared emission bands, providing new traces for developing tunable laser and optoelectronic devices.application/htmlengMultidisciplinary Digital Publishing Institute (MDPI)CHurn:issn: 2571-6131info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/4.0/Repositorio Institucional - UlimaUniversidad de Limareponame:ULIMA-Institucionalinstname:Universidad de Limainstacron:ULIMAGlassIonsAbsorption spectraLuminescenceRaman spectroscopyPhononsLasersOptoelectronic devicesAlkali metalsMolecular structureMolecular spectroscopyhttps://purl.org/pe-repo/ocde/ford#2.01.00Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glassesinfo:eu-repo/semantics/articleArtículo en ScopusIngeniería CivilIngeniería IndustrialDepartment of Civil Engineering, Universidad de LimaLICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.ulima.edu.pe/bitstream/20.500.12724/19068/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD53CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-81037https://repositorio.ulima.edu.pe/bitstream/20.500.12724/19068/2/license_rdf8fc46f5e71650fd7adee84a69b9163c2MD5220.500.12724/19068oai:repositorio.ulima.edu.pe:20.500.12724/190682025-09-03 17:20:24.778Repositorio Universidad de Limarepositorio@ulima.edu.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Influence of Alkali Metal Ions on the Structural and Spectroscopic Properties of Sm3+-Doped Silicate Glasses
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