Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares

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This research was funded by the Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica-Concytec (Project: Equipamiento Científico 2018-01/E044-2018-01-BM, Contrato N◦ 012-2018-Fondecyt/BM) of the Peruvian Government, The World Bank Group, the Universidad Nacional Toribio Rodríguez de Mendo...

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Autores: Castro Alayo, Efraín Manuelito, Torrejón-Valqui Lliseli, Cayo-Colca, Ilse Silvia, Cárdenas Toro, Fiorella
Formato: artículo
Fecha de Publicación:2021
Institución:Consejo Nacional de Ciencia Tecnología e Innovación
Repositorio:CONCYTEC-Institucional
Lenguaje:inglés
OAI Identifier:oai:repositorio.concytec.gob.pe:20.500.12390/3192
Enlace del recurso:https://hdl.handle.net/20.500.12390/3192
https://doi.org/10.3390/foods10123101
Nivel de acceso:acceso abierto
Materia:Sacha Inchi oil
Cocoa butter
Chocolate
Raman mapping
https://purl.org/pe-repo/ocde/ford#2.11.01
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dc.title.none.fl_str_mv Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
title Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
spellingShingle Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
Castro Alayo, Efraín Manuelito
Sacha Inchi oil
Cocoa butter
Chocolate
Raman mapping
https://purl.org/pe-repo/ocde/ford#2.11.01
title_short Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
title_full Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
title_fullStr Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
title_full_unstemmed Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
title_sort Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares
author Castro Alayo, Efraín Manuelito
author_facet Castro Alayo, Efraín Manuelito
Torrejón-Valqui Lliseli
Cayo-Colca, Ilse Silvia
Cárdenas Toro, Fiorella
author_role author
author2 Torrejón-Valqui Lliseli
Cayo-Colca, Ilse Silvia
Cárdenas Toro, Fiorella
author2_role author
author
author
dc.contributor.author.fl_str_mv Castro Alayo, Efraín Manuelito
Torrejón-Valqui Lliseli
Cayo-Colca, Ilse Silvia
Cárdenas Toro, Fiorella
dc.subject.none.fl_str_mv Sacha Inchi oil
topic Sacha Inchi oil
Cocoa butter
Chocolate
Raman mapping
https://purl.org/pe-repo/ocde/ford#2.11.01
dc.subject.es_PE.fl_str_mv Cocoa butter
Chocolate
Raman mapping
dc.subject.ocde.none.fl_str_mv https://purl.org/pe-repo/ocde/ford#2.11.01
description This research was funded by the Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica-Concytec (Project: Equipamiento Científico 2018-01/E044-2018-01-BM, Contrato N◦ 012-2018-Fondecyt/BM) of the Peruvian Government, The World Bank Group, the Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas and the Pontificia Universidad Católica del Perú. The APC was funded by the Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica-Concytec.
publishDate 2021
dc.date.accessioned.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.available.none.fl_str_mv 2024-05-30T23:13:38Z
dc.date.issued.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12390/3192
dc.identifier.doi.none.fl_str_mv https://doi.org/10.3390/foods10123101
dc.identifier.scopus.none.fl_str_mv 2-s2.0-85122022990
url https://hdl.handle.net/20.500.12390/3192
https://doi.org/10.3390/foods10123101
identifier_str_mv 2-s2.0-85122022990
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv urn:issn:2304-8158
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.uri.none.fl_str_mv https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONCYTEC-Institucional
instname:Consejo Nacional de Ciencia Tecnología e Innovación
instacron:CONCYTEC
instname_str Consejo Nacional de Ciencia Tecnología e Innovación
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spelling Publicationrp05878600rp05882600rp05877600rp03812600Castro Alayo, Efraín ManuelitoTorrejón-Valqui LliseliCayo-Colca, Ilse SilviaCárdenas Toro, Fiorella2024-05-30T23:13:38Z2024-05-30T23:13:38Z2021https://hdl.handle.net/20.500.12390/3192https://doi.org/10.3390/foods101231012-s2.0-85122022990This research was funded by the Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica-Concytec (Project: Equipamiento Científico 2018-01/E044-2018-01-BM, Contrato N◦ 012-2018-Fondecyt/BM) of the Peruvian Government, The World Bank Group, the Universidad Nacional Toribio Rodríguez de Mendoza de Amazonas and the Pontificia Universidad Católica del Perú. The APC was funded by the Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica-Concytec.Cocoa butter (CB) is an ingredient traditionally used in the manufacturing of chocolates, but its availability is decreasing due to its scarcity and high cost. For this reason, other vegetable oils, known as cocoa butter equivalents (CBE), are used to replace CB partially or wholly. In the present work, two Peruvian vegetable oils, coconut oil (CNO) and sacha inchi oil (SIO), are proposed as novel CBEs. Confocal Raman microscopy (CRM) was used for the chemical differentiation and polymorphism of these oils with CB based on their Raman spectra. To analyze their miscibility, two types of blends were prepared: CB with CNO, and CB with SIO. Both were prepared at 5 different concentrations (5%, 15%, 25%, 35%, and 45%). Raman mapping was used to obtain the chemical maps of the blends and analyze their miscibility through distribution maps, histograms and relative standard deviation (RSD). These values were obtained with multivariate curve resolution–alternating least squares. The results show that both vegetable oils are miscible with CB at high concentrations: 45% for CNO and 35% for SIO. At low concentrations, their miscibility decreases. This shows that it is possible to consider these vegetable oils as novel CBEs in the manufacturing of chocolates.Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - ConcytecengMDPIurn:issn:2304-8158info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/4.0/Sacha Inchi oilCocoa butter-1Chocolate-1Raman mapping-1https://purl.org/pe-repo/ocde/ford#2.11.01-1Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squaresinfo:eu-repo/semantics/articlereponame:CONCYTEC-Institucionalinstname:Consejo Nacional de Ciencia Tecnología e Innovacióninstacron:CONCYTECTHUMBNAIL2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdf.jpg2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdf.jpgIM Thumbnailimage/jpeg13636https://repositorio.concytec.gob.pe/bitstreams/03c25ce8-5ac7-a402-793b-e5ffe24afc48/download374184ebeafbf9259e76d64ba82de6f4MD52ORIGINAL2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdf2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdfapplication/pdf4923921https://repositorio.concytec.gob.pe/bitstreams/4ab73d23-ee45-23bd-81e2-104dcc8a093b/downloadde40cdb614b05a32d1ea561bd4eca6aeMD51TEXT2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdf.txt2021_Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution.pdf.txtExtracted texttext/plain63497https://repositorio.concytec.gob.pe/bitstreams/c3b126e9-fb07-49f9-8b6f-508f0c3c5a4b/download3f31f2baac66abd244d62e375b13bb7fMD5320.500.12390/3192oai:repositorio.concytec.gob.pe:20.500.12390/31922024-06-19 21:01:46.627https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessopen accesshttps://repositorio.concytec.gob.peRepositorio Institucional CONCYTECrepositorio@concytec.gob.pe#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#<Publication xmlns="https://www.openaire.eu/cerif-profile/1.1/" id="0f4dd3d8-6f11-437e-a4a5-6a40d8e7bf81"> <Type xmlns="https://www.openaire.eu/cerif-profile/vocab/COAR_Publication_Types">http://purl.org/coar/resource_type/c_1843</Type> <Language>eng</Language> <Title>Evaluation of the Miscibility of Novel Cocoa Butter Equivalents by Raman Mapping and Multivariate Curve Resolution–Alternating Least Squares</Title> <PublishedIn> <Publication> <Title>urn:issn:2304-8158</Title> </Publication> </PublishedIn> <PublicationDate>2021</PublicationDate> <DOI>https://doi.org/10.3390/foods10123101</DOI> <SCP-Number>2-s2.0-85122022990</SCP-Number> <Authors> <Author> <DisplayName>Castro Alayo, Efraín Manuelito</DisplayName> <Person id="rp05878" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Torrejón-Valqui Lliseli</DisplayName> <Person id="rp05882" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Cayo-Colca, Ilse Silvia</DisplayName> <Person id="rp05877" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> <Author> <DisplayName>Cárdenas Toro, Fiorella</DisplayName> <Person id="rp03812" /> <Affiliation> <OrgUnit> </OrgUnit> </Affiliation> </Author> </Authors> <Editors> </Editors> <Publishers> <Publisher> <DisplayName>MDPI</DisplayName> <OrgUnit /> </Publisher> </Publishers> <License>https://creativecommons.org/licenses/by-nc-nd/4.0/</License> <Keyword>Sacha Inchi oil</Keyword> <Keyword>Cocoa butter</Keyword> <Keyword>Chocolate</Keyword> <Keyword>Raman mapping</Keyword> <Abstract>Cocoa butter (CB) is an ingredient traditionally used in the manufacturing of chocolates, but its availability is decreasing due to its scarcity and high cost. For this reason, other vegetable oils, known as cocoa butter equivalents (CBE), are used to replace CB partially or wholly. In the present work, two Peruvian vegetable oils, coconut oil (CNO) and sacha inchi oil (SIO), are proposed as novel CBEs. Confocal Raman microscopy (CRM) was used for the chemical differentiation and polymorphism of these oils with CB based on their Raman spectra. To analyze their miscibility, two types of blends were prepared: CB with CNO, and CB with SIO. Both were prepared at 5 different concentrations (5%, 15%, 25%, 35%, and 45%). Raman mapping was used to obtain the chemical maps of the blends and analyze their miscibility through distribution maps, histograms and relative standard deviation (RSD). These values were obtained with multivariate curve resolution–alternating least squares. The results show that both vegetable oils are miscible with CB at high concentrations: 45% for CNO and 35% for SIO. At low concentrations, their miscibility decreases. This shows that it is possible to consider these vegetable oils as novel CBEs in the manufacturing of chocolates.</Abstract> <Access xmlns="http://purl.org/coar/access_right" > </Access> </Publication> -1
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